Wear full protective equipment, including suitable respiratory protection. 4.3 Indication of any immediate medical attention and special treatment needed No data available SECTION 5: Firefighting measures 5.1 Extinguishing media Suitable extinguishing media Dry powder 5.2 Special hazards arising from the substance or mixture Carbon oxides, Nitrogen oxides (NOx), Sulphur oxides, Potassium oxides 5.3 Advice for firefighters 1. Strong oxidizer. 333-20-0 Data on potassium thiocyanate, a very similar chemical: Human oral TDLo: 428 mg/kg, toxic psychosis, hallucinations, distorted perceptions, gastritis. Product: Potassium Thiocyanate Revision Date: 07/17/2013 3/7 Special Protective Equipment As in any fire, wear MSHA/NIOSH approved (or equivalent) self-contained positive pressure I'm concerned about the information that KSCN can be used to resemble fake blood and stigmata; this may encourage some readers of the article to try this on their own hands and skins, yet the article doesn't mention any of the health risks, although the word "harmful" does appear. Inhalation: Causes irritation to the respiratory tract. Potassium Thiocyanate Safety data sheet According to 1907/2006/EC (REACH), 2015/830/EU SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1 Product identifier:Potassium thiocyanate ... 5.2 Special hazards arising from the substance or mixture: May cause mild irritation to the skin and eyes. In recent years thiocyanates have been used enthusiastically. Hazardous combustion products: Hydrogen cyanide. May cause kidney damage. Potassium permanganate decomposes hydrogen The compound has a low melting point relative to most other inorganic salts. 3 Effective date : 12.16.2014 Page 2 of 7 Sodium Thiocyanate, Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com Health Hazards! 7757-79-1 Potassium nitrate >99 231-818-8 Section 3 - Hazards Identification EMERGENCY OVERVIEW Appearance: white. Product name : Potassium thiocyanate Product Number : 207799 Brand : Sigma-Aldrich Index-No. Ingestion: May cause psychosis, vomiting, disorientation, weakness, low blood pressure, convulsions and death which may be delayed. May be harmful if swallowed. Potassium Permanganate being conveyed through propylene tube ignited the tube. 333-20-0 Potassium Thiocyanate <1.0 % 206-370-1 Hazard Symbols: XN Risk Phrases: 21/22 32 Section 3 - Hazards Identification EMERGENCY OVERVIEW Appearance: clear, colorless liquid. Hygroscopic 6. 594 mg/kg [Mouse]. Potential Health Effects Eye: May cause eye irritation. Target Organs: Heart, brain. Potassium thiocyanate is the chemical compound with the molecular formula KSCN. Duration of … Ph Eur Page 2 of 13 The life science business of Merck operates as MilliporeSigma in the US and Canada Acute toxicity, Category 4, Oral, H302 Acute toxicity, Category 4, Inhalation, H332 Acute toxicity, Category 4, Dermal, H312 Serious eye damage, Category 1, H318 The story of the thiocyanates began in 1903 with Pauli, who suggested the use of potassium thiocyanate as a hypotensive agent. Potassium thiocyanate 333-20-0 100 Toxicological Data on Ingredients: Potassium thiocyanate: ORAL (LD50): Acute: 854 mg/kg [Rat]. When solid hydroxylamine is brought into contact with solid potassium permanganate, there is produced immediately a with flame. It has a role as a human metabolite. Special hazards arising from the substance or mixture If this product is involved in a fire, the following can be released: Carbon monoxide and carbon dioxide Sulfur oxides (SOx) ... Potassium Thiocyanate (Potassium Rhodanide) is generally immediately available in most volumes. SECTION 6. Potassium Thiocyanate,ACS Created by Global Safety Management, 1-813-435-5161 - www.GSMSDS.com Control Parameters: 333 - 20 - 0, Potassium thiocyanate, TWA 5 mg/m3 USA. Section 6. * Eye wash fountains should be provided in the immediate work area for emergency use. Relevant identified uses of the substance or mixture and uses advised against Recommended Use Laboratory chemicals. Special Remarks on Fire Hazards: Spontaneously flammable on contact with ethylene glycol. Sigma-Aldrich offers a number of Potassium thiocyanate products. It is a pseudohalide anion and a sulfur molecular entity. EUH statements: EUH032 Contact with acids liberates very toxic gas. High purity, submicron and nanopowder forms may be considered. 3. 1.3 Details of the supplier of the safety data sheet Company : Central Drug House (P) Ltd 7/28 Vardaan House New Delhi-10002 INDIA : 333-20-0 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses : Laboratory chemicals, Manufacture of substances 1.3 Details of the supplier of the safety data sheet Caution! Potassium Thiocyanate 1. Danger! Special controls should be in place for highly toxic chemicals or when significant skin, eye, or breathing exposures are possible. : P/7280/50, P/7280/53 Synonyms Potassium rhodanide CAS-No 333-20-0 EC-No. Section 3: Hazards Identification Potential Acute Health Effects: Hazardous in case of skin contact (irritant, permeator), of eye contact (irritant), of ingestion, of inhalation (lung irritant). Hazards Identification. May cause irritation. Special hazards arising from the substance or mixture No additional information available 5.3. Special hazards arising from the substance or mixture No additional information available 5.3. Pennsylvania Right To Know Components Potassium thiocyanate CAS-No. Label elements Signal Word Warning Hazard Statements H412 - Harmful to aquatic life with long lasting effects : 333-20-0 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses : Laboratorychemicals, Industrial & for professional use only. Hazard Identification Hazardous in case of skin contact (irritant, permeator), of eye contact (irritant), of ingestion, of inhalation (lung SARA 311/312 Hazards No SARA Hazards Massachusetts Right To Know Components No components are subject to the Massachusetts Right to Know Act. It has a role as a human metabolite. May cause eye, skin, and respiratory tract irritation. ... individuals who have been informed of the hazards of exposure to Potassium Permanganate. Special hazards arising from the substance or mixture If this product is involved in a fire, the following can be released: Carbon monoxide and carbon dioxide Sulfur oxides (SOx) Nitrogen oxides (NOx) Potassium oxide Advice for firefighters Protective equipment: Wear self-contained respirator. Special Equipment and Precautions: Use water to cool nearby containers and structures. ECOLOGICAL INFORMATION 12.1 Toxicity no data available 12.2 Persistence and degradability no data available 12.3 Bioaccumulative potential Hazards Identification Emergency Overview-----WARNING! Human oral LDLo: 80 mg/kg, hallucinations, distorted perceptions, convulsions, muscle weakness. Accidental release measures Product name Potassium thiocyanate for analysis EMSURE® ACS,ISO,Reag. Contains: Potassium thiocyanate 2.3 Other hazards. Wear fully protective impervious suit. 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